A two-stage flowsheet that pairs an anaerobic digester (for bulk COD reduction + biogas recovery) with a downstream microbial fuel cell that polishes residual COD into direct electrical current. The AD does the thermodynamic heavy lifting; the MFC monetises what’s left as electrons rather than gas, with no biogas-handling burden on the back end.
Key Differentiators
AD alone leaves 25–50 % of the influent COD behind in the digestate. An MFC polish step recovers a portion of that residual COD as electricity at electrode-surface efficiencies that exceed dark-fermentation H2 routes. Bridges the parameter-sweep page’s Butler-Volmer + Monod outputs (sweep export → MESSanUnit) directly into a full-flowsheet TEA.
How It Works
Influent enters the AD; biogas exits the dome to CHP; digestate flows by gravity into the MFC anode chamber where exoelectrogens (Geobacter / mixed consortia) attach to a carbon-cloth or graphite-felt anode. Substrate oxidation releases electrons that travel through an external circuit to an air cathode (typical) and protons migrate through a separator. Power is dumped to a buck-boost charger that conditions the MFC output to grid-tie or battery voltage.
Performance Envelope
MFC power density0.1–2 W/m² anode area
MFC coulombic efficiency15–40 % on real wastewater
Combined COD removal75–95 % (AD + MFC)
Electrical output1–10 GWh/yr at 500 m² anode
LCoE (current scale)$100–500/kWh (not yet competitive)
Research Status
MFCs remain at TRL 4–5 outside niche sensor applications. The MFC+AD combination is published (Logan group, Penn State 2010s) but no pilot plants are continuously operated. Active research: scaling anode area while preserving CE, cheaper cathode catalysts, hybrid AD-MFC operating strategies.
Reactor Geometry
Left: cylindrical AD tank (see "wastewater-ad" for sizing). Right: rectangular MFC chamber with planar anode (left wall) and air cathode (right wall, typically Pt/C on carbon cloth or activated-carbon-on-stainless-mesh). Top: external circuit with adjustable load resistor; LED indicator on the wire visualises current.
Applications
- Wastewater treatment with energy recovery (food / dairy / brewery effluents)
- Decentralised treatment at sites without grid access
- BOD sensors at WWTP outfalls (MFC voltage tracks BOD)
- Educational / public-engagement reactors
- Combined heat (AD biogas) + power (MFC) micro-grids
Active Volume
0.5 – 50 m³ MFC stack downstream of a 10 000 m³ AD